首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6759篇
  免费   836篇
  国内免费   151篇
化学   5297篇
晶体学   99篇
力学   245篇
综合类   2篇
数学   115篇
物理学   1988篇
  2023年   66篇
  2022年   93篇
  2021年   226篇
  2020年   352篇
  2019年   243篇
  2018年   168篇
  2017年   176篇
  2016年   303篇
  2015年   309篇
  2014年   345篇
  2013年   443篇
  2012年   398篇
  2011年   362篇
  2010年   274篇
  2009年   371篇
  2008年   399篇
  2007年   495篇
  2006年   360篇
  2005年   294篇
  2004年   227篇
  2003年   266篇
  2002年   205篇
  2001年   177篇
  2000年   148篇
  1999年   153篇
  1998年   158篇
  1997年   70篇
  1996年   70篇
  1995年   72篇
  1994年   48篇
  1993年   56篇
  1992年   46篇
  1991年   41篇
  1990年   37篇
  1989年   32篇
  1988年   32篇
  1987年   23篇
  1986年   30篇
  1985年   25篇
  1984年   23篇
  1983年   7篇
  1982年   12篇
  1981年   11篇
  1980年   19篇
  1979年   18篇
  1978年   14篇
  1977年   13篇
  1976年   10篇
  1974年   8篇
  1973年   6篇
排序方式: 共有7746条查询结果,搜索用时 812 毫秒
1.
An electromechanical integrated electrostatic harmonic actuator is promising for the miniaturization of electromechanical devices. As the dimensions of the actuator decrease, the effects of the van der Waals force become obvious. In this study, by considering the nonlinearity of electrostatic and van der Waals forces, nonlinear vibration equations of the flexible ring of an electrostatic harmonic actuator are deduced. Using these equations, the nonlinear free vibration and nonlinear forced response of the actuator are investigated. The effects of the van der Waals force on the nonlinear vibration of the flexible ring are analyzed. Results show that these effects of the van der Waals force are relatively obvious under some conditions and should be considered.  相似文献   
2.
Secondary structures tend to be recognizable because they have repeating structural motifs, but mimicry of these does not have to follow such well-defined patterns. Bioinformatics studies to match side-chain orientations of a novel hydantoin triazole chemotype ( 1 ) to protein-protein interfaces revealed it tends to align well across parallel and antiparallel sheets, like rungs on a ladder. One set of these overlays was observed for the protein-protein interaction uPA⋅uPAR. Consequently, chemotype 1 was made with appropriate side-chains to mimic uPA at this interface. Biophysical assays indicate these compounds did in fact bind uPAR, and elicit cellular responses that affected invasion, migration, and wound healing.  相似文献   
3.
Doxorubicin (DOX), a recognized anticancer drug, forms stable associations with carbon nanotubes (CNTs). CNTs when properly functionalized have the ability to anchor directly in cancerous tumors where the release of the drug occurs thanks to the tumor slightly acidic pH. Herein, we study the armchair and zigzag CNTs with Stone–Wales (SW) defects to rank their ability to encapsulate DOX by determining the DOX-CNT binding free energies using the MM/PBSA and MM/GBSA methods implemented in AMBER16. We investigate also the chiral CNTs with haeckelite defects. Each haeckelite defect consists of a pair of square and octagonal rings. The armchair and zigzag CNT with SW defects and chiral nanotubes with haeckelite defects predict DOX-CNT interactions that depend on the length of the nanotube, the number of present defects and nitrogen doping. Chiral nanotubes having two haeckelite defects reveal a clear dependence on the nitrogen content with DOX-CNT interaction forces decreasing in the order 0N > 4N > 8N. These results contribute to a further understanding of drug-nanotube interactions and to the design of new drug delivery systems based on CNTs.  相似文献   
4.
We describe the synthesis and the physical properties of polyaromatic hydrocarbons (PAHs) containing a phosphorus atom at the edge. In particular, the impact of the successive addition of aromatic rings on the electronic properties was investigated by experimental (UV/Vis absorption, fluorescence, cyclic voltammetry) and theoretical studies (DFT). The physical properties recorded in solution and in the solid state showed that the P‐containing PAHs exhibit properties expected for an emitter in white organic light‐emitting diodes (WOLEDs).  相似文献   
5.
6.
7.
Diffraction in electron stimulated desorption has revealed a propensity for Cl+ desorption from rest atom vs. adatom areas and unfaulted vs. faulted zones of Cl-terminated Si(1 1 1)-(7 × 7) surfaces. We associate the 15 eV ± 1 eV threshold with ionization of Si-Cl σ-bonding surface states and formation of screened two-hole states with Si 3s character. Similar specificity is observed from A and B reconstructions. This can be due to reduced screening in unfaulted regions and increased hole localization in Si back-bonds within faulted regions.  相似文献   
8.
A new unified electroweak model is proposed in this paper. In this unified electroweak model, Higgsmechanism is not used, so no Higgs particle exists in the model. In order to keep the masses of intermediate gaugebosons non-zero, two sets of gauge fields will be introduced. In order to introduce symmetry breaking and to help tointroduce the masses of all fields, a vacuum potential is needed. Except for those terms concerning Higgs particle, thefundamental dynamical properties of this model are similar to those of the standard model. And in a proper limit, thismodel will approximately return to the standard model. The purpose of this paper is not to say that the Higgs particledoes not exist in Nature, it is only to prove that, without a Higgs particle, we can also set up a unified electroweak modelwhich is consistent with present experiments.  相似文献   
9.
The European Physical Journal A - The ω-meson photoproduction, γ + p→p + ω, is studied in the framework of a model, containing π-meson exchange in t-channel and...  相似文献   
10.
Basic principles of the generalized lattice model of multicomponent condensed systems are formulated. Short-range parts of interatomic interactions are taken into account by means of the geometric constraints method. Long-range parts of the interactions are taken into account in mean field approximation. The expression for Helmholtz free energy is obtained. A system of integral equations for the equilibrium distributions of components is derived. The asymptotic properties of its solutions are investigated. Moment expansion of interatomic interactions and localization of integral terms in free energy is obtained. A Ginzburg–Landau-like functional of free energy is derived.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号